Analytical Sciences

Determination of Polymeric Aluminum in Soil Extracted with a Modified Anion-Exchange Resin as a Solid-Phase Adsorbent by ICP-AES

Mingbiao LUO,*^,** Shuping BI,*  Chenyi WANG,* and Junzhong HUANG**

*Department of Chemistry, Nanjing University, Nanjing, 210093, P. R. China
**Department of Applied Chemistry, East China Institute of Technology, Jiangxi 344000, P. R. China

In the present work, a new method was established by applying solid-phase extraction (SPE) to preconcentrate and separate polymeric aluminum (Al) and using ICP-AES to determine the polymeric Al, the total monomeric Al, and the total Al in soil extracts, respectively. A modified resin was prepared with impregnated 8-hydroxyquinoline-5-sulfoxinate (HQS) on the anion-exchange resin. It has good recognition ability for Al fractions, compared to the commonly used cation ion-exchange resin, which has a better ability to adsorb cations and a weak ability to recognize detailed Al species. The optimum conditions for Al fractionation sorption, elution and separation and the interference of foreign ions were studied with the prepared resin by continuous column and batch procedures. Monomeric Al was bound to Pyrocathecol Violet (PCV) at pH 6.2, whereas the polymeric Al species did not react with PCV for at least 15 min. Because a stable complex of Al-PCV was not absorbed on the HQS modified resin, the polymeric Al could be preconcentrated on-line by the HQS-modified resin. The adsorbed polymeric Al was eluted with 3 mL of 3 mol L^-1 of HCl, and then detected by ICP-AES. The method has been applied to directly determine polymeric Al in soil extracts with high selectivity as well as a high preconcentration factor. It gives a limit of detection of 0.6 ng mL^-1 with a relative standard deviation of less than 5.7% (n = 5, 0.24 μg mL^-1 Al).

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