Abstract − Analytical Sciences, 19(4), 643 (2003).
Crystal Structure of (5,14-Methyl-7,12-dimethyl-1,4,8,11-tetraazadiiminecyclotetradecylene-N,N',N",N'")nickel(II) Bis-(diisopropyldithiophosphate) Complex
Fangfang JIAN, Kui JIAO, Faqian LIU, and Qingxiang WANG
New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China
The macrocyclic tetradentate Ni(II) compound was obtained in a reaction and determined by X-ray diffraction. The crystal structure shows that the molecule is centrosymmetric, and Ni atom located in a square planar coordination environment. The two [(iPrO)2PS2]- anions are outside the macrocycle complex to balance. The Ni-N bond lengths are in the range of 1.906(2) to 1.950(2)Å.
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