Analytical Sciences

Kinetically Controlled Separation of Cadmium(II) from Zinc(II) with Dithizone in the Presence of Nitrilotriacetic Acid

Hideyuki ITABASHI,  Masaki YOSHIDA, and Hiroshi KAWAMOTO

Department of Applied Chemistry, Faculty of Engineering, Gunma University, Kiryu, Gunma 376-8515, Japan

The extraction rates of cadmium(II) and zinc(II) with dithizone (H₂dz) in the presence of nitrilotriacetic acid (NTA) were measured, and the possible kinetic separation of cadmium(II) from zinc(II) was investigated. Upon the addition of NTA, the difference in the extraction rate between cadmium(II) and zinc(II) became large. Based on the observed rate constant under the condition [NTA] = 1 x 10^-2 mol dm^-3, [H₂dz]_org = 1 x 10^-3 mol dm^-3, and pH = 7.0, the shaking time required for the quantitative separation of cadmium(II) from zinc(II) was calculated to be between 326 and 995 s. The experimental results agreed with the prediction, and the quantitative separation of cadmium(II) from zinc(II) was performed within the above-mentioned range of shaking times.

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