Analytical Sciences

Abstract − Analytical Sciences, 37(10), 1401 (2021).

Feasibility Studies of X-Ray Computed Tomography for Forensic Examination of Single Fibers
Wataru TADANO,*1,*2 Eishi TANABE,*3 Jens R. STELLHORN,*4 Kenji KOMAGUCHI,*4 Masaru TAKEUCHI,*1 and Shinjiro HAYAKAWA*4
*1 Forensic Science Laboratory, Hiroshima Prefectural Police H.Q., 2-26-3 Konan, Naka, Hiroshima 730-0825, Japan
*2 Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Japan
*3 West Region Industrial Research Center, Hiroshima Prefectural Technology Research Institute, 3-13-26 Kagamiyama, Higashi-Hiroshima 739-0046, Japan
*4 Department of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima 739-8527, Japan
Non-destructive observations of cross-sectional shapes of acrylic single fibers using X-ray computed tomography (CT) were performed. A commercial X-ray CT apparatus (Rigaku nano3DX) was employed because of its micrometer-scale spatial resolution and remarkable image contrast for soft matter. We assessed two types of sample support, a paraffin strip and a nylon string, for single fiber samples in terms of easy handling and sample recovery. Fixed individual single fibers were loaded into a narrow polyimide tube in both cases, and the tube ensured that the sample remained in the field of view during the CT measurements. In both cases, the cross-sectional shapes of individual single fibers could be distinguished, with a circular shape for one sample and a triangular shape for the other. However, the support using a nylon string was found to be more suitable for further analysis. The cross-sectional profile of the obtained tomographic image showed a clear difference between polyimide and nylon. The intensity ratio or the image contrast corresponded to that of the local densities. It was also found that the effect of the artifact appeared at around the boundaries of the objects, but the local density could still be utilized for examining individual single fibers.