Analytical Sciences

Abstract − Analytical Sciences, 20(3), 495 (2004).

Determination of a Polymeric Hindered Amine Light Stabilizer in Polypropylene Formulated with Magnesium Hydroxide Flame Retardant by Reactive Thermal Desorption-Gas Chromatography
Yoshihiko TAGUCHI,* Yasuyuki ISHIDA,** Hajime OHTANI,* Hiroyuki BEKKU,*** and Masaya SERA***
*Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan
**Research Center for Advanced Energy Conversion, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan
***Tsutsunaka Plastic Industry Co., Ltd., 1-2, Techno-park Nara, Sugawa-cho, Gojyo, Nara 637-0014, Japan
A polymeric hindered amine light stabilizer (HALS), Tinuvin 622 (MW 4000), in PP materials formulated with a magnesium hydroxide flame retardant was determined by reactive thermal desorption (RTD) gas chromatography (GC). Two kinds of the HALS components that were formed through the RTD in the presence of tetramethylammonium hydroxide [(CH3)4NOH, TMAH] were clearly observed in the chromatograms of the PP samples, with negligible interference from the other additives and the PP substrate. Here, the coexisting flame retardant was proved to affect significantly the RTD process of the occluded HALS. As a result, the recovery of the HALS components in the RTD-GC chromatograms of the PP samples increased with increase in the content of the flame retardant. This enhancement of the HALS recovery is attributed mainly to the preferential exposure of the HALS on the surface of the ground PP sample through the interaction between the polymeric HALS and the flame retardant in the molten PP during kneading. In spite of such a considerable action of the flame retardant, the observed intensities of the characteristic peaks of HALS by RTDGC showed a good linear relationship with the HALS content in the PP samples with constant content of the flame retardant (50 phr); this relationship could be used as the calibration line for the determination of the polymeric HALS in the PP materials containing the flame retardant.