Analytical Sciences

Abstract − Analytical Sciences, 20(1), 165 (2004).

A Simple in situ Visual and Tristimulus Colorimetric Method for the Determination of Trace Arsenic in Environmental Water after Its Collection on a Mercury(II)-Impregnated Paper
Md. Mustafizur RAHMAN,* Kaoru FUJINAGA,** Yasushi SEIKE,** and Minoru OKUMURA** 
*Interdisciplinary Graduate School of Science and Engineering, Shimane University, Matsue 690-8504, Japan
**Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, Matsue 690-8504, Japan
A simple in situ visual and tristimulus colorimetric method for the determination of trace arsenic in environmental water after collecting arsenic on a test paper impregnated with mercury(II) bromide and rosaniline chloride by its reduction aeration has been developed. The color development on the test paper is based on the formations of AsH(HgBr)2 (yellow) and/or As(HgBr)3 (brownish yellow) by a reaction between mercury(II) bromide and arsine (AsH3), which is produced through the reduction of As(III) (arsenite ion) and/or As(V) (arsenate ion) in a sample solution. To a sample solution, potassium iodide, tin(II) chloride, zinc sand and 4 ml of 6 M hydrochloric acid solution were added successively. The liberated arsine was collected on the test paper. The yellow or brownish-yellow color intensity on the test paper was measured by a tristimulus colorimeter and also by a visual method. The established method is applicable to the determination of arsenic in environmental water sample such as river, brackish, and seawater types.